The is the 1965 Topps, number 321 in the '65 Topps baseball card set, autographed by Le Grande Orange, Daniel Joseph Staub.
Rusty Staub was an All-Star performer for the Houston Colt 45's, Houston Astros, Montreal Expos, New York Mets, and Detroit Tigers. He is also an All-Star restauranteur and chef.
This is a great signature and was signed for me over 40 years ago.